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            | Snowflake
            Designer's Page ... Engineering the perfect snowflake ...
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        | Build a
        better snowflake, and the world will shovel a path to your door.  --KGL |  
        | A number of researchers have grown snow
        crystals in the laboratory using several different methods.  Some of these methods
        are described here, along with pictures of the resulting synthetic snow crystals. |  
        | Free-fall
        Growth |  
        |   The simplest technique for growing snow crystals is to allow the crystals to fall freely
        in a cold chamber.  The images at right show a sketch of such a chamber, and few
        sample crystals growth with this method [1].  Many additional images can be found in Free-falling
        Snow. Since cold air is denser than warm air, the air in the cold chamber doesn't
        mix much with the outside air, even with the top cover removed.  To supersaturate the
        air one needs only to breathe into the box, or use a humidifier, to produce a dense
        fog.  Within this cloud the water vapor pressure is then roughly equal to the water
        saturation pressure, which is supersaturated about 5-15 percent relative to the ice
        saturation vapor pressure (see Ice Properties). 
        The droplets do not spontaneously freeze until the temperature approaches -40 C, so ice
        crystals must be nucleated in the cloud.  Various smokes will provide suitable
        nucleation sites, and dropping a small pellet of dry ice (which cools the air right around
        it to -60 C) will also produce a fine cloud of sparkling ice crystals.
 The tiny ice crystals grow rapidly in the supersaturated air, and fall very
        slowly since their terminal velocity in air is low.  As they grow larger, they fall
        faster, and typically reach the chamber floor no larger than 0.1 mm.  Large numbers
        of crystals can be formed in this way.  In spite of their small size, with a good
        microscope a wide variety of morphologies can be observed using this simple technique.
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        | Growth
        in a Moving Air Column |  
        |    A variation on the
        free-fall technique is to use a moving column of air, adjusting the air flow speed to
        equal the crystal's terminal velocity, so that it remains suspended as it grows [2]. By
        using a tapered column the resulting air flow tends to stabilize the crystals in the
        horizontal direction. This technique provides a very close match to natural snowfall, and
        growth times of up to 30 minutes have been demonstrated.  Since a growing crystal
        exhibits substantial random motion in the moving airstream, each crystal must be removed
        from the growth chamber for observation.   Not surprisingly, snow crystals grown
        using this technique bear an excellent resemblance to natural snow crystals. |  
        | Growth
        on a Filament |  
        |  To grow larger snow crystal under better controlled conditions, it is necessary to support
        the crystal as it grows.  A thin filament is an obvious solution to the support
        problem, and Nakaya used various filaments to grow the first artificial snow crystals in
        the 1930's.   Nakaya used a convection chamber, which is shown in the image at
        right.  Warm water produced water vapor at the bottom of the chamber, which was
        carried up to the growth region by convection.  Convection produces a somewhat
        erratic airflow, and the filament does interfere with the crystal growth, but nevertheless
        Nakaya was able to use this technique with great success (see Photo Collections). It's interesting to note that Nakaya realized his best snow crystals using a
        stretched rabbit hair filament (he also tried spider web and other exotic materials).
          The advantage of rabbit hair was that crystals tended to nucleate at only a few
        places along the hair, so fairly isolated crystals could be grown.  I tried this a
        few times, but never with any real success -- wrong kind of rabbit, perhaps!
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        |  A
        great advance introduced by Mason and collaborators was the use of a water vapor diffusion
        chamber, which is shown at right [3] (see Designer
        Snowflakes).  The diffusion chamber has warm moist air at the top, just the
        opposite of the convection chamber.  The water vapor diffuses down from the top,
        producing cool supersaturated air in the middle of the chamber.  Since the chamber is
        warm on top and cold on the bottom, convection is suppressed, resulting in very stable
        conditions for snow crystal growth. The vertical temperature gradient in the diffusion chamber can also be put to
        advantage, as was shown by Mason et al.  If a long string, such as a piece of nylon
        fishing line, is hung down the center of the chamber, then ice crystals will grow all
        along the string.  In this way one can immediately observe the different growth
        morphologies as a function of growth temperature (see the Snowflake Primer).
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        | Growth
        on a Substrate |  
        |   A number of workers studying
        snow crystal growth have made observations of crystals grown on a substrate. 
        Although the substrate definitely perturbs the growth to some extent, the effects are not
        too bad if the supersaturation is low and the substrate is clean.  In this case
        crystals will not spontaneously nucleate on the substrate, and thus isolated samples can
        be observed.Some of the best pictures were obtained by Gonda and coworkers [4], who
        developed a technique by which snow crystals are grown directly on a sapphire
        window.  Supersaturated air is produced in a growth chamber, and silver iodide smoke
        is introduced to nucleate the production of snow crystals.  The crystals grow for a
        bit while suspended in the air, then fall onto the window, where further growth can be
        photographed.  The technique clearly produces nice symmetrical snow crystals (see the
        examples below), which can be observed using a microscope objective positioned directly
        underneath the substrate for high-resolution imaging.  The technique seems to work
        best for plate-like crystals and low supersaturations, where the perturbations from the
        substrate are minimal.
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        |     Above are samples of snow crystals grown on a substrate, published by T. Gonda and
        coworkers in the Journal of Crystal Growth [4].
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        | Growth
        of Electrodynamically Levitated Crystals |  
        |  A novel approach to producing artificial snow crystals is to levitate the
        growing crystals in an electrodynamic trap (a Paul-type ion trap). Such a scheme produces
        isolated single crystals, since the levitated crystal doesn't touch anything
        directly.  Growing large crystals using this technique is difficult, however, since
        as the weight of the crystal increases it quickly becomes too heavy to support in the
        trap.  Electrodynamic traps for ice crystal growth were first demonstrated by B.
        Swanson and collaborators [5], and more on this subject can be found at the Ice
        Particle Microphysics Laboratory. 
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        | Growth
        on Ice Needles |  
        |  Our favorite technique for growing snow crystals is to grow them on the ends of long ice
        needles, and many examples can be found in our (see Designer
        Snowflakes).   This method was first applied by Bartlett, van den Heuval, and
        Mason in 1963 [6], when they discovered that ice crystals growing under the influence of a
        large applied voltage developed into long thin ice needles (for details of this see Electric
        Growth). We have found that electric needles grown along
        the c-axis are wonderfully well suited for producing isolated snow crystals, particularly
        large stellar crystals. By first growing a single electric needle to a length of ~1 cm,
        subsequent crystal growth at the end of the needle is quite unperturbed by the underlying
        support. Also the electric needles are thin and strong, and hold a growing snow crystal
        quite rigidly for sharp photography.
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        | Growth
        under Unusual Conditions |  
        |   Nearly all the work on snow crystal growth done to date has been under normal
        atmospheric conditions, i.e. with standard atmospheric pressure and standard atmospheric
        constituents.  Growth under different background pressures and in different gases has
        been realized, however, and with interesting results.  Under higher pressures, for
        example, the diffusion constant decreases, leading to "enhanced" growth
        morphologies -- thinner plates and longer needles than occur under normal
        conditions.  There is also evidence that the kinetic growth coefficients depend on
        background gas.Finally, a number of workers (including the author) have found that trace
        chemical impurities in the background air can greatly affect snow crystal growth, a topic
        which has not been well studied to date.
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        | 
 
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        | [1] V. J. Schaefer and J. A. Day, Peterson
        Field Guides: Atmosphere (Houghton Mifflin, 1981). [2] T. Takahashi and N. Fukuta, J. Meteor. Soc. Japan 66,
        841 (1988); T. Takahashi, T. Endoh, G. Wakahama, and N Fukuta, J. Meteor. Soc. Japan
        69, 15 (1991).
 [3] B. Mason, in The Physics of Clouds (Oxford University Press, 1971).
 [4] T. Gonda, S. Nakahara, and T. Sei, J. Cryst. Growth 99,
        183 (1990); T. Gonda and S. Nakahara, J. Cryst. Growth 160, 162
        (1996); T. Gonda and S. Nakahara, J. Cryst. Growth 173, 189
        (1997)].
 [5] B. D. Swanson, N. Bacon, E. J. Davis and M. B. Baker, Q. J. Roy. Meteor.
        Soc. 125, 1039 (1999).
 [6] J. T. Bartlett, A. P. van den Heuval, B. J. Mason, Z. angue. Math. Phys.
        14, 509 (1963).
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